Journal of Organic Chemistry p. 5115 - 5119 (1985)
Update date:2022-08-03
Topics:
Pews, R. Garth
Lysenko, Zenon
Halogenated acetonitriles add smoothly to acrolein, methacrolein, and methacrolein dimethyl acetal in the presence of a catalytic amount of CuCl and triphenylphosphine, tri-n-butylphosphine, or triethylamine to give halogenated difunctional adducts.The adducts have been cyclized in high yields under acidic conditions to halogenated pyridines.
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