INSECT PHEROMONES AND THEIR ANALOGS. XLVII. SYNTHESIS OF 11-OXODODECA-3,6-DIYNOIC ACID - THE ACYCLIC PRECURSOR OF A MACROLIDE COMPONENT OF PHEROMONES OF Oryzaephilus mercator AND O. surinamensis

DOI: 10.1007/BF00630126

Source and publish data:

Chemistry of Natural Compounds p. 240 - 244 (1993)

Update date:2022-07-29

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Authors:

Odinokov, V. N.

Ishmuratov, G. Yu.

Kharisova, R. Ya.

Vakhidov, R. R.

Botsman, L. P.

Tolstikov, G. A.

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Article abstract of DOI:10.1007/BF00630126

A new approach is proposed to the synthesis of 11-oxododeca-3,6-diynoic acid - the acyclic precursor of a macrolide component of pheromones of Oryzaephilus mercator and O. surinamensis - from the readily available tetrahydropyran or allylacetone via the intermediate 5-bromo-2,2-ethylenedioxypentane.

Full text of DOI:10.1007/BF00630126

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