NOVEL SYNTHESIS OF β-SILOXY ESTERS BY CONDENSATION OF CARBONYLS AND TRIMETHYLSILANE WITH α,β-UNSATURATED ESTERS CATALYZED BY RhCl3

DOI: 10.1016/S0040-4039(00)96631-0

Source and publish data:

Tetrahedron Letters p. 4809 - 4812 (1987)

Update date:2022-08-05

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Authors:

Revis, Anthony

Hilty, Terrence K.

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Article abstract of DOI:10.1016/S0040-4039(00)96631-0

A novel one pot reaction of α,β-unsaturated esters with carbonyls and trimethylsilane gave good yields of β-siloxy esters.This RhCl3 catalyzed method improves upon the two step reaction of silyl ketene acetals with carbonyls.

Full text of DOI:10.1016/S0040-4039(00)96631-0

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