Tetrahedron p. 155 - 166 (1986)
Update date:2022-08-04
Topics:
Gavina, F.
Luis, S. V.
Costero, A. M.
Evidence is presented demonstrating the existence of free dehydrobenzenes in the thermal decomposition of diaryliodonium-2-carboxylates, and that o-benzyne itself and its 4-methyl-, 4-chloro-, 4-bromo- and 4-nitro-derivatives are generated from insoluble polymer-bound precursors and trapped by a second solid phase in Diels-Alder reactions.Lifetimes for these elusive species are determined.
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