Bulletin of the Chemical Society of Japan p. 209 - 213 (1984)
Update date:2022-07-31
Topics:
Arase
Hoshi
Masuda
To synthesize internal alkenyldialkylboranes, coupling reactions were carried out by using 1-halo-1-alkenyldialkylboranes and Grignard reagents. Hydrogen peroxide oxidation and protonolysis with acetic acid of the reaction product revealed that internal (E)-alkenyldialkylborane was formed in 60-90% yield.
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