Archiv der Pharmazie p. 408 - 410 (1984)
Update date:2022-08-03
Topics:
Boehme, Horst
Braun, Guenther
Organolithium compounds 2 derived from diphenylketimine N,S-acetals of type 1 are shown to react with benzaldehyde or benzophenone at the acetal carbon yielding secondary and tertiary alcohols of type 3.Analogously, treatment of 2 with methyl iodide affords 4, whereas benzyl chloride attacks the diphenylmethylene carbon to form 5.Acid-catalysed hydrolysed hydrolysis of 5 yields the hitherto unknown 1,1,2-triphenylethylamine (6)
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