Journal of Organic Chemistry p. 2837 - 2838 (1984)
Update date:2022-08-05
Topics:
Ikeda, Takafumi
Hutchinson, C. Richard
A total synthesis of optically active cyclopentanoid monoterpenes (iridoids) can be achieved by using (-)-(1S,5R)-cis-3-oxabicyclo<4.3.0>non-7-en-2-one (1) to prepare a key bicyclic synthon, (+)-7.The generality and enantiospecificity of this approach is demonstrated by the preparation of (-)-1-O-methylsweroside aglucon (8).
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