Palladium-catalyzed addition of hexamethylditin to allenes

DOI: 10.1021/om00086a036

Source and publish data:

Organometallics p. 1318 - 1320 (1984)

Update date:2022-08-03

Topics:

Authors:

Killing, Hubertus

Mitchell, Terence N.

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Article abstract of DOI:10.1021/om00086a036

Hexamethylditin adds readily to allenes in the presence of Pd(PPh₃)₄; unsymmetrically substituted alienes undergo kinetically controlled addition at lower temperatures, while at higher temperatures the thermodynamically more stable p

Full text of DOI:10.1021/om00086a036

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