Transformations of a μ2-Vinyl Ligand at a Dimanganese Centre and the Flexibility of μ2-Acyl Ligands; X-Ray Crystal Structures of 2-H)2-C(O)CPh:CHPh>(μ2-PPh2)(CO)6>, 2-C(O)CPh:CHPh>(μ2-PPh2)(CO)6(CNBut)2>, and 3-P(Ph)2CH:CH2>(C...

DOI: 10.1039/c39840000209

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 209 - 211 (1984)

Update date:2022-07-30

Topics:

Authors:

Henrick, Kim

Iggo, Jonathan A.

Mays, Martin J.

Raithby, Paul R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39840000209

2-?:η²-CR:CHR)(μ₂-PPh2)(CO)7> (R = H or Ph) reacts with 2-electron donor ligands to give μ₂-acyl complexes or products containing the P(Ph)2CR:CHR ligand; these correspond, respectively, to insertion of CO or PPh2 into the ?-bond between the metal and the μ₂-vinyl group.

Full text of DOI:10.1039/c39840000209

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Mn2(μ-PPh2CH=CH2)(CO)7(CNBu(t))

Cas No:90898-21-8

R&D Labs maybe for 90898-21-8

Shijiazhuang City Xiehe Pharmaceutical Co., Ltd

Contact:+86-311-80817929

Address:Shangzhuang,Shijiazhuang,China
shijiazhuang shuanglian chemical industry co.,ltd

Contact:0311-82190302

Address:Luquan Intersection , Shijiazhuang--Taiyuan Expressway，Shijiazhuang City
Xuzhou Tianrun Chemical Co.,Ltd

website:http://www.tianrunchem.cn

Contact:86-516-83832636

Address:fuxing road
Shanghai Bocimed Pharmaceutical Co., Ltd.

website:http://www.bocimed.com

Contact:+86-21-68861632

Address:Building 1, Lane 647, Songtao Road, Zhangjiang High-Tech Park, Shanghai
Deltachem(QingDao)Co.,Ltd.

Contact:+8618766299236

Address:ROOM808, BUILDING2,NO.230 SHEN ZHEN ROAD, LAOSHAN DISTRICT

Relevant to this article

Ligand substitution in HC(O)CCo₃(CO)₉ with 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): Diphosphine ligand fluxionality, decarbonylation of the formyl moiety and competitive P-Ph bond cleavage reactivity

Doi:10.1016/j.jorganchem.2006.05.029
(2006)
Novel Family of Heterocyclic Strained Helices. Cesium-Assisted Syntheses and Conformational and Chirooptical Properties and Geometries

Doi:10.1021/jo00193a010
(1984)
Inhibitors of epidermal growth factor receptor tyrosine kinase: Optimisation of potency and in vivo pharmacokinetics

Doi:10.1016/j.bmcl.2006.06.054
(2006)
A combinatorial approach towards the synthesis of non-hydrolysable triazole-iduronic acid hybrid inhibitors of human α-l-iduronidase: Discovery of enzyme stabilizers for the potential treatment of MPSI

Doi:10.1039/c7cc09642a
(2018)
Platinum-catalyzed hydrative cyclization of 1,6-diynes for the synthesis of 3,5-substituted conjugated cyclohexenones

Doi:10.3390/molecules15075045
(2010)
Doi:10.1021/ja01237a028
(1944)

Article Doi