Transformations of a μ2-Vinyl Ligand at a Dimanganese Centre and the Flexibility of μ2-Acyl Ligands; X-Ray Crystal Structures of 2-H)2-C(O)CPh:CHPh>(μ2-PPh2)(CO)6>, 2-C(O)CPh:CHPh>(μ2-PPh2)(CO)6(CNBut)2>, and 3-P(Ph)2CH:CH2>(C...

DOI: 10.1039/c39840000209

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 209 - 211 (1984)

Update date:2022-07-30

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Authors:

Henrick, Kim

Iggo, Jonathan A.

Mays, Martin J.

Raithby, Paul R.

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Article abstract of DOI:10.1039/c39840000209

2-?:η²-CR:CHR)(μ₂-PPh2)(CO)7> (R = H or Ph) reacts with 2-electron donor ligands to give μ₂-acyl complexes or products containing the P(Ph)2CR:CHR ligand; these correspond, respectively, to insertion of CO or PPh2 into the ?-bond between the metal and the μ₂-vinyl group.

Full text of DOI:10.1039/c39840000209

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