Stable and Explosive Alkali Metal-Anion Radical-Ammonia Complexes

DOI: 10.1021/jo00192a060

Source and publish data:

Journal of Organic Chemistry p. 3443 - 3444 (1984)

Update date:2022-08-04

Topics:

Authors:

Stevenson, Gerald R.

Peterson, Richard A.

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Article abstract of DOI:10.1021/jo00192a060

Solid crystalline Rb and Cs salts with the composition M⁺2(NH3)(naphthalene^-.)2 have been generated and are found to hold the ammonia molecule endothermically, and similar salts involving alkaline earth metals or alkali metals with other anion radicals detonate upon crystallization due to the exothermic release of ammonia.

Full text of DOI:10.1021/jo00192a060

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