Reaction of α-(N-carbamoyl)alkylcuprates with enantioenriched propargyl electrophiles: Synthesis of enantioenriched 3-pyrrolines

DOI: 10.1021/jo061442h

Source and publish data:

Journal of Organic Chemistry p. 8755 - 8760 (2006)

Update date:2022-08-05

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Authors:

Dieter, R. Karl

Chen, Ningyi

Gore, Vinayak K.

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Article abstract of DOI:10.1021/jo061442h

Enantioenriched propargyl mesylates or perfluorobenzoates react with α-(N-carbamoyl)alkylcuprates to afford scalemic α-(N-carbamoyl) allenes which undergo N-Boc deprotection and AgNO₃-promoted cyclization to afford N-alkyl-3-pyrrolines. The syn

Full text of DOI:10.1021/jo061442h

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