ETHYLENIC ACYL CYANIDES IV : INTRAMOLECULAR ENE CYCLISATION OF 5-METHYL-5-HEXENOYL CYANIDES TO 3-METHYL-2-CYCLOHEXENONES

DOI: 10.1016/S0040-4039(01)80187-8

Source and publish data:

Tetrahedron Letters p. 1463 - 1466 (1984)

Update date:2022-07-29

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Authors:

El-Abed, Douniazad

Jellal, Abdelkebir

Santelli, Maurice

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Article abstract of DOI:10.1016/S0040-4039(01)80187-8

Condensation of methallyltrimethylsilanes with α,β-ethylenic acyl cyanides leads to 5-methyl-5-hexenoyl cyanides which after thermal cyclisation give 3-methyl-2-cyclohexenones and hydrogen cyanide.

Full text of DOI:10.1016/S0040-4039(01)80187-8

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