Journal of the American Chemical Society p. 13640 - 13648 (2006)
Update date:2022-08-04
Topics:
Jasti, Ramesh
Rychnovsky, Scott D.
Isotopic labeling experiments were performed to elucidate a new mechanism for racemization in Prins cyclization reactions. The loss in optical activity for these reactions was shown to occur by 2-oxonia-Cope rearrangements by way of a (2)-oxocarbenium ion
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