Stereoconservative Reductive Methyl- and Dimethylamination of Isomeric 3,3-Diarylpropenals. Synthetic and Mechanistic Studies on Control of the Stereochemistry

DOI: 10.1021/jo00196a021

Source and publish data:

Journal of Organic Chemistry p. 4209 - 4214 (1984)

Update date:2022-08-04

Topics:

Authors:

Hoegberg, Thomas

Ulff, Bengt

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Article abstract of DOI:10.1021/jo00196a021

The tertiary allylic amine zimeldine (1Z) and the secondary amine 2Z have been prepared by reductive aminations of (Z)-3-(4-bromophenyl)-3-(3-pyridyl)propenal (3Z) with sodium cyanoborohydride in the presence of dimethylammonium and methylammonium chlorid

Full text of DOI:10.1021/jo00196a021

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Product name:2-Propen-1-amine, 3-(4-bromophenyl)-N-[3-(4-bromophenyl)-3-(3-pyridinyl)-2-propenyl]-N- methyl-3-(3-pyridinyl)-, (Z,Z)-

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