Intramolecular and Intermolecular Lewis Acid Catalyzed Ene Reactions Using Ketones as Enophiles

DOI: 10.1021/jo00195a022

Source and publish data:

Journal of Organic Chemistry p. 3988 - 3994 (1984)

Update date:2022-08-05

Topics:

Authors:

Jackson, Andrew C.

Goldman, Boris E.

Snider, Barry B.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00195a022

Alkylaluminium halide catalyzed intramolecular ene reactions of β-keto esters proceed in high yield to give cyclohexanols, via either a type I or type II process.Treatment of β-keto ester 3 with Me2AlCl gives cis-fused ene adduct 5 in 67percent yield.Simi

Full text of DOI:10.1021/jo00195a022

Products guided by the article

Product name:Cyclohexanecarboxylic acid, 1-(4-methyl-4-pentenyl)-2-oxo-, ethyl ester

Cas No:91781-77-0

R&D Labs maybe for 91781-77-0

Tianjin Dongchang Fine Chemical Industry Co., Ltd.

Contact:+86-22-29894595

Address:Economic Developing Zone, Ji County, Tianjin, China
Shanghai Sinofluoro Scientific Co., Ltd

Contact:+86-21-64279360

Address:Room 1006,Building 3,#58 East Xinjian Road, Shanghai ,201100,China,
Jiangxi Province Bethel Pharmaceutical Co., Ltd.

Contact:+86-795-259 3456 ，+86-15957688008 13566650571

Address:Huangjindui Chemical Park， Shanggao County ，Yichun city，Jiangxi Province
Aminodiscovery Co.,Ltd.

Contact:+86-535-8888888

Address:No.161 Haishi Rd.
Allright GC (Jinan) Biotechnology Ltd.

website:https://www.argcbiotech.com/

Contact:86-18405413579-

Address: No.27566 of Jingshiroad, Huaiyin District, Jinan City(250011), Shandong Province, China.

Relevant to this article

Synthesis and characterisation of complexes of Group 13 metal amidinate heterocycles with the CpFe(CO)₂ fragment

Doi:10.1039/b611758a
(2006)
Palladium-Catalyzed One-Pot Conversion of Aldehydes and Ketones into 4-Substituted Homopropargyl Alcohols and 5-En-3-yn-1-ols ?

Doi:10.1021/acs.joc.7b01529
(2017)
Synthesis and Claisen rearrangement of bridged bicyclic enol ethers of relevance to the course of ketene s-cis-diene cycloaddition

Doi:10.1039/b611311g
(2006)
Development of a Multi-Kilogram-Scale Synthesis of AZD1283: A Selective and Reversible Antagonist of the P2Y₁₂ Receptor

Doi:10.1021/op400288v
(2013)
New α-substituted succinate-based hydroxamic acids as TNFα convertase inhibitors

Doi:10.1021/jm990377j
(1999)
Dinuclear cationic zirconium complexes with the fulvalene ligand. Synthesis and reactivity

Doi:10.1016/S0022-328X(97)00212-X
(1997)

Article Doi