Intramolecular and Intermolecular Lewis Acid Catalyzed Ene Reactions Using Ketones as Enophiles

DOI: 10.1021/jo00195a022

Source and publish data:

Journal of Organic Chemistry p. 3988 - 3994 (1984)

Update date:2022-08-05

Topics:

Authors:

Jackson, Andrew C.

Goldman, Boris E.

Snider, Barry B.

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Article abstract of DOI:10.1021/jo00195a022

Alkylaluminium halide catalyzed intramolecular ene reactions of β-keto esters proceed in high yield to give cyclohexanols, via either a type I or type II process.Treatment of β-keto ester 3 with Me2AlCl gives cis-fused ene adduct 5 in 67percent yield.Simi

Full text of DOI:10.1021/jo00195a022

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