Relative Reactivities of Some Polycyclic Aromatic Hydrocarbons in Catalytic Hydrogenation over Raney Nickel

DOI: 10.1246/bcsj.66.670

Source and publish data:

Bulletin of the Chemical Society of Japan p. 670 - 672 (1993)

Update date:2022-08-02

Topics: Steric hindrance Substituents Ring Fusion

Authors:

Minabe, Masahiro

Urushibara, Shuuichi

Mishina, Fumihiko

Kimura, Takao

Tsubota, Motohiro

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Article abstract of DOI:10.1246/bcsj.66.670

Catalytic hydrogenation of 9H-fluorene (10), phenanthrene (2), 4H-cyclopentaphenanthrene (3), pyrene (4), and fluoranthene (5) was carried out over Raney nickel (W-7) at 323 K under 608 kPa of hydrogen.The order of the reaction rate was 5>4>3>2>1.The adsorption equilibrium constant of the substrates decreased in the order 4 > or = 5 >> 2 > 3 >> 1.

Full text of DOI:10.1246/bcsj.66.670

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