N,O-Silatropic Rearrangements. Enhanced Silyl Group Exchange between Nitrogen and Oxygen via Chelation to Nickel and X-ray Crystal Structure of a Substituted N,O-Disilylimidate Moiety

DOI: 10.1021/ja00335a022

Source and publish data:

Journal of the American Chemical Society p. 6993 - 6999 (1984)

Update date:2022-09-26

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Authors:

Fryzuk, Michael D.

MacNeil, Patricia A.

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Article abstract of DOI:10.1021/ja00335a022

The nickel(II) hydrocarbonyl complexes Ni(R) (R = methyl, allyl, vinyl, and phenyl) react with 1 atm of carbon monoxide at room temperature to generate nickel(0) dicarbonyl derivatives .Loss of one CO ligand from the vinyl deriv

Full text of DOI:10.1021/ja00335a022

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