Hydrofluoric Acid Catalyzed Intramolecular Diels-Alder Reactions

DOI: 10.1021/jo00198a018

Source and publish data:

Journal of Organic Chemistry p. 4674 - 4682 (1984)

Update date:2022-08-03

Topics:

Authors:

Roush, William R.

Gillis, Herbert R.

Essenfeld, Amy P.

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Article abstract of DOI:10.1021/jo00198a018

Studies of catalysis of intramolecular Diels-Alder reactions of trienes activated with substituted 2-hydroxyethyl esters are described.Triene esters 1, 11, 22, and 26 cyclize in moderate to good yield (44-78percent) when exposed to aqueous HF in acetonitr

Full text of DOI:10.1021/jo00198a018

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