Direct Disulfide Formation from 2-Quinolinylmethyl Thioethers with Iron(III) or Copper(II) Salt

DOI: 10.1246/cl.1993.803

Source and publish data:

Chemistry Letters p. 803 - 806 (1993)

Update date:2022-08-03

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Authors:

Yoshizawa, Hidenori

Otaka, Akira

Habashita, Hiromu

Fujii, Nobutaka

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Article abstract of DOI:10.1246/cl.1993.803

2-Quinolinylmethyl thioethers were efficiently cleaved to generate the corresponding symmetrical disulfides using the following systems; FeCl3/N,N-dimethylformamide (DMF)/H2O, FeCl3/ethanol (EtOH)/H2O, and CuCl2/DMF/H2O.The 2-quinolinylmethyl group was utilized as a thiol protecting group in the synthesis of a model peptide.

Full text of DOI:10.1246/cl.1993.803

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