Lewis acid mediated asymmetric [2,3]-sigmatropic rearrangement of allylic amines. Scope and mechanistic investigation

DOI: 10.1021/jo062178v

Source and publish data:

Journal of Organic Chemistry p. 1294 - 1300 (2007)

Update date:2022-08-02

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Authors:

Blid, Jan

Panknin, Olaf

Tuzina, Pavel

Somfai, Peter

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Article abstract of DOI:10.1021/jo062178v

(Chemical Equation Presented) The first asymmetric [2,3]-sigmatropic rearrangement of achiral allylic amines has been realized by quaternization of the amines with an enantiomerically pure diazaborolidine and subsequent treatment with Et₃N. The

Full text of DOI:10.1021/jo062178v

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