Synthesis and reactivity of (μ-η2:η2-peroxo)dicopper(II) complexes with dinucleating ligands: Hydroxylation of xylyl linker with a NIH shift

DOI: 10.1016/j.jorganchem.2006.05.068

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Journal of Organometallic Chemistry p. 111 - 121 (2007)

Update date:2022-08-05

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Authors:

Matsumoto, Takahiro

Furutachi, Hideki

Nagatomo, Shigenori

Tosha, Takehiko

Fujinami, Shuhei

Kitagawa, Teizo

Suzuki, Masatatsu

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Article abstract of DOI:10.1016/j.jorganchem.2006.05.068

New hexadentate dinucleating ligands having a xylyl linker, X-L-R, were synthesized, where X-L-R = 1,3-bis[bis(6-methyl-2-pyridylmethyl)aminomethyl]-2,4,6-trimethybenzene (Me₂-L-Me) and 1,3-bis[bis(6-methyl-2-pyridylmethyl)aminomethyl]-2-fluoro

Full text of DOI:10.1016/j.jorganchem.2006.05.068

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Product name:1,3-bis[bis(6-methyl-2-pyridylmethyl)aminomethyl]-2,4,6-trimethylbenzene

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