NUCLEOPHILIC SUBSTITUTION OF α-HALO-KETONES-XXII ACETOLYSIS OF α'-PHENOXY-α-CHLORO-KETONES. A COMPARISON OF THEIR REACTIVITY WITH THAT OF THE CORRESPONDING THIOETHERS

DOI: 10.1016/S0040-4020(01)91146-9

Source and publish data:

Tetrahedron p. 1893 - 1900 (1984)

Update date:2022-08-05

Topics: Reactivity Nucleophilic substitution Thioethers Comparison Acetolysis

Authors:

Pusino, A.

Rosnati, V.

Saba, A.

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Article abstract of DOI:10.1016/S0040-4020(01)91146-9

The results obtained in the acetolysis of α-chloro-ketones 1 a-e are compared with those previously reported for the acetolysis of the corresponding α'-phenylthio-α-chloro-ketones 15a-e and discussed in terms of the enolization-solvolysis mechanisms.

Full text of DOI:10.1016/S0040-4020(01)91146-9

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