SYNTHESIS OF 3-O-ACETYL-2,6-DIAZIDO-4-O-BENZYL-2,6-DIDEOXY-L-IDOPYRANOSYL CHLORIDE, A GLYCOSYL HALIDE FOR THE SYNTHESIS OF NEOMYCIN B

Article abstract of DOI:10.1016/0008-6215(84)85278-7

3-O-Acetyl-2,6-diazido-4-O-benzyl-2,6-dideoxy-L-idopyranosyl chloride, a glycosyl halide useful for the synthesis of neomycin B, has been prepared from D-glucose.Key steps in this synthesis are the introduction of two azido groups at C-5 and -1 (after red