4,4'-Methylenebis(benzyne) Equivalent

DOI: 10.1021/jo00200a012

Source and publish data:

Journal of Organic Chemistry p. 5084 - 5087 (1984)

Update date:2022-09-26

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Authors:

Nakayama, Juzo

Sakai, Atsuhiro

Hoshino, Masamatsu

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Article abstract of DOI:10.1021/jo00200a012

The aprotic diazotization of 5,5'-methylenebis(anthranilic acid) (4) by isoamyl nitrite in refluxing 1,2-dichloroethane functions as a 4,4'-methylenebis(benzyne) (5) equivalent. 5 undergoes Diels-Alder reaction with tetraphenylcyclopentadienone, anthracen

Full text of DOI:10.1021/jo00200a012

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