Tetrahedron Letters p. 2869 - 2872 (1984)
Update date:2022-08-05
Topics:
Souppe, J.
Namy, J-L.
Kagan, H.B.
Acid chlorides react with SmI2 to give α-diketones.Various experiments show that the initially formed acyl radical is rapidly transformed into an acyl anion which is thus generated by quite an unusual route.This species acylates acid chlorides, aldehydes and ketones in situ to give α-diketones and α-diketols.There are some limitations to this acyl anion chemistry but the reactions are realized with a good efficiency at room temperature in THF solution.
View Morewebsite:http://www.greenutra.cn
Contact:0086-411-39553357
Address:No. 7-1-1802, Huizhi Garden,Ocean Square,Dalian, 116033, China
Shandong LuZhou Amino Acid Co., Ltd
Contact:86-539-2218025
Address:yishui economic and technical development zone zhenxing south road
Nanjing distinctions Medical Technology Co., Ltd.(expird)
Contact:+86-15996203785 13914714059
Address:nanjing,jiangsu , China
shijiazhuang baisheng chem co.; ltd
Contact:86-0311-80790826
Address:shijiazhuang hebei
Taizhou KEDE Chemical.Co.,Ltd.
Contact:86-576-84613060
Address:Jiangkou Chemical Zoon
Doi:10.1007/BF03019864
(1959)Doi:10.1016/j.jorganchem.2006.10.048
(2007)Doi:10.1016/S0040-4020(01)88436-2
(1984)Doi:10.1039/c4cc07392d
(2015)Doi:10.1021/ol0630189
(2007)Doi:10.1515/znb-2009-0606
(2009)
