Tetrahedron Letters p. 2869 - 2872 (1984)
Update date:2022-08-05
Topics:
Souppe, J.
Namy, J-L.
Kagan, H.B.
Acid chlorides react with SmI2 to give α-diketones.Various experiments show that the initially formed acyl radical is rapidly transformed into an acyl anion which is thus generated by quite an unusual route.This species acylates acid chlorides, aldehydes and ketones in situ to give α-diketones and α-diketols.There are some limitations to this acyl anion chemistry but the reactions are realized with a good efficiency at room temperature in THF solution.
View MoreKangZhiYuan Pharmaceutical Company Limited
Contact:(Sabrina)86-20-85273232
Address:4th floor, building B, Dadi industry zone, Tangxia, Tianhe, Guangzhou, China
ShangHai Ruiyi Medical Technology Co.,Ltd.
Contact:+86-21-54718086
Address:No951 Jianchuan RD，Minhang District
Contact:+86-10-62651721
Address:29 Yongxing Road, Daxing District,Beijing China
Contact:+86-571-86025531 / 86024803
Address:1218-24 Guangyin Mansion,42 Fengqi East Road
Puyang Willing Chemicals Co.,Ltd.
Contact:86-393-4840366
Address:Puyang Henan China
Doi:10.1007/BF03019864
(1959)Doi:10.1016/j.jorganchem.2006.10.048
(2007)Doi:10.1016/S0040-4020(01)88436-2
(1984)Doi:10.1039/c4cc07392d
(2015)Doi:10.1021/ol0630189
(2007)Doi:10.1515/znb-2009-0606
(2009)
