N-(TRIMETHYLSILYLMETHYL)AMINOMETHYL ETHERS AS AZOMETHINE YLIDE SYNTHONS. A NEW AND CONVENIENT ACCESS TO PYRROLIDINE DERIVATIVES

DOI: 10.1246/cl.1984.1117

Source and publish data:

Chemistry Letters p. 1117 - 1120 (1984)

Update date:2022-08-02

Topics:

Authors:

Hosomi, Akira

Sakata, Yasuyuki

Sakurai, Hideki

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Article abstract of DOI:10.1246/cl.1984.1117

The title compounds, readily prepared from (trimethylsilylmethyl)amines, formaldehyde and an alcohol, react with electron deficient alkenes in the presence of iodosilane or silyl triflate in combination with cesium fluoride to give the corresponding pyrrolidine derivatives stereospecifically in excellent yield.

Full text of DOI:10.1246/cl.1984.1117

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