Tetrahedron Letters p. 5451 - 5454 (1989)
Update date:2022-08-04
Topics:
Bakker, Bert H.
Cerfontain, Hans
The small differences in the rate coefficients of β-sultone formation between the internal and the terminal double bond in the octenes 2a-c and (Z)-1,10-nonadecadiene are evidence for a concerted cycloaddition of sulfur trioxide.The formation of β-sultone 1d is accompanied by 15percent of 2-octene-1-sulfonic acid, formed in a primary side-reaction.The sulfonation of the octenes 2a-d to their β-sultones 1a-d is reversible.Desulfonation of the β-sultones 1a-d by water to the olefins 2a-d proceeds in a stereospecific syn fashion.
View MoreJiangXi Hong Run Chemical Co., Ltd
Contact:+86-0791-88521351
Address:XingHuo industrial zone in YongXiu county
Contact:--
Address:80G, No.1 Building, Guodu Development Mansion, No. 182 Zhaohui Road, Hangzhou City, Zhejiang Province,China.
Contact:0086-22-2822 1962 / 2822 1963
Address:B-808, No. 1, North-South Street, Hexi District,
Shanghai ZaiQi Bio-Tech Co., Ltd.,
Contact:+86-21-5482 4098
Address:Bldg. No.7, No.201 MinYi Rd，Songjiang CaoHeJing High-Tech Park Shanghai 201516 P,R,China
Changsha Goomoo Chemical Technology Co.Ltd
Contact:+86-731-82197655
Address:No.649,Chezhan Rd.(N),Changsha,Hunan,China
Doi:10.1055/s-0034-1378858
(2015)Doi:10.1002/chem.201302327
(2013)Doi:10.1016/j.bmc.2013.01.011
(2013)Doi:10.1016/j.bmc.2013.09.065
(2013)Doi:10.1039/DT9840001703
(1984)Doi:10.1055/s-2007-990935
(2008)
