Journal of the Chemical Society, Dalton Transactions p. 1703 - 1708 (1984)
Update date:2022-08-04
Topics:
Hussain, Wasif
Leigh, G. Jeffery
Ali, Hapipah Mohd.
Pickett, Christopher J.
Rankin, Douglas A.
The preparation of a series of complexes < M(N2)2<(p-XC6H4)2PCH2CH2P(C6H4X-p)2>2 > (M=Mo or W) is described.The variation of oxidation potential with phosphine substituents suggests that the electronic structures involve through-metal conjugation between the phosphine phosphorus and the dinitrogen, which contributes to the strength of the metal-dinitrogen bond.Electron-donating substituents on the phosphine make the compounds easier to oxidise.Studies of the rate of replacement of dinitrogen by benzonitrile show that electron-donating substituents also increase the metal-dinitrogen bond lability.
Jiangsu King Road New Materials Co., Ltd.
website:http://www.jskingroad.com
Contact:0519-85720726 0519-85720721 15006126856
Address:No.1,Weihua Road,Xinbei District,Changzhou City,Jiangsu Province
Huaian Double Win Chemicals Co.,Ltd.
Contact:+86-13511538872
Address:Blk 43,Greenland Century Town,Huaian District, Huaian City,Jiangsu Province,China
Shanghai SMEC Trading Co., Ltd.
website:http://www.shanghaismec.com
Contact:+86-21-68811293
Address:ROOM 1101,NO.800 SHANGCHENG RD,SHANGHAI,CHINA
ShangHai Original Economy-Trade Develop Co.,Ltd.,
Contact:86-21-68552131
Address:shanghai
Hebei Lead Bio-Chemicals Co., Ltd.
website:http://www.ldbiochem.com
Contact:+86-311-87826503
Address:481, Heping West Road, Shijiazhuang,China
Doi:10.1021/jo01026a501
(1964)Doi:10.1016/j.jorganchem.2006.12.030
(2007)Doi:10.1016/j.tetlet.2005.06.044
(2005)Doi:10.1246/bcsj.35.111
(1962)Doi:10.3184/030823410X12812894581758
(2010)Doi:10.1021/jo062114k
(2007)
