Tetrahedron Letters p. 3479 - 3482 (1982)
Update date:2022-08-04
Topics:
Hoffmann, Reinhard W.
Helbig, Wilfried
Ladner, Wolfgang
Diastereoselective and enantioselective reduction of the β-ketoester 3 by yeast to 4 provided the chiral starting material for a synthesis of 4RS,6S,7S-serricornine, having the same configuration as the natural product.This material was converted into optically active and diastereomerically pure 6S,7S-anhydro-serricornine (2).
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