Journal of Molecular Structure p. 202 - 207 (2007)
Update date:2022-07-31
Topics:
Jin, Feng
Li, Jian-feng
Zhou, Hong-ping
Wu, Jie-ying
Yang, Jia-xiang
Tian, Yu-peng
Jiang, Min-hua
A novel imidazole derivative, 1-[trans-4-(4-diethylaminostyryl)phenyl]imidazole (abbreviated as L), and its complex Zn(SCN)2L2 have been synthesized and fully characterized. Their crystal structures have been determined by X-ray diffraction. The molecular structure of L is approximately coplanar, the bond lengths of C-C and C-N are located between the normal double and single bonds, which show that L has a delocalized π-electron system in the molecule. In the molecular structure of Zn(SCN)2L2, zinc atom is four coordinated by two nitrogen atoms of the ligands (L) and two nitrogen atoms of thiocyanate to form a distorted tetrahedral geometry. The one-dimensional structure of Zn(SCN)2L2 is formed by C-H?S interactions and π-π interactions. They both crystallize in the noncentrosymmetric space group P21, and exhibit powder second-harmonic generation (SHG) efficiency approximately twenty times high as that of urea, indicating promising potential applications as useful nonlinear optical (NLO) materials.
View MoreYanCheng LongShen Chemical Co.,Ltd.
Contact:+86-515-86668866
Address:No.13,Weiyi Road,Funing Aoyang Industrial Park
Shanghai Bocimed Pharmaceutical Co., Ltd.
website:http://www.bocimed.com
Contact:+86-21-68861632
Address:Building 1, Lane 647, Songtao Road, Zhangjiang High-Tech Park, Shanghai
Shanghai Synmedia Chemical Co., Ltd
Contact:+86-21-38681880
Address:6th Floor, 11A Building, No.528 Ruiqing Road, Heqing town, Pudong new district, Shanghai China
Suzhou Tianma Specialty Chemicals Co.,Ltd
Contact:+86-512-68090577
Address:#199, Huayuan Rd, Mudu, Suzhou, Jiangsu, CHINA
Reliable Pharma Technology (Shanghai) Co., Ltd.
Contact:0086-21-67676847-8008
Address:Lane 1500, No.68, Xinfei Road, Songjiang District, Shanghai, 201611, P.R.China.
Doi:10.1002/ejic.200600258
(2006)Doi:10.1016/0040-6031(84)87188-9
(1984)Doi:10.1016/j.tet.2007.01.007
(2007)Doi:10.1021/jo0620720
(2007)Doi:10.1016/j.tetlet.2005.12.026
(2006)Doi:10.1021/om00120a019
(1985)