Organic Letters p. 1105 - 1108 (2007)
Update date:2022-07-29
Topics:
Wen, Shijun
Carey, Krystle L.
Nakao, Yoichi
Fusetani, Nobuhiro
Packham, Graham
Ganesan
(Chemical Equation Presented) The unprecedented diastereoselective Mannich reaction of a Z-allylsulfoximine was a key step in the total synthesis of the marine natural products azumamide A and E, and an unnatural analogue. Their relative potency as histone deacetylase inhibitors was evaluated and found to correlate with predicted zinc-binding affinity.
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