ADDITION REACTIONS OF ETHOXYCARBONYLNITRENE AND ETHOXYCARBONYLNITRENIUM ION TO ALLYLIC ETHERS

DOI: 10.1016/S0040-4039(01)81414-3

Source and publish data:

Tetrahedron Letters p. 4271 - 4274 (1984)

Update date:2022-08-05

Topics:

Authors:

Loreto, M. Antonietta

Pellacani, Lucio

Tardella, Paolo A.

Toniato, Elena

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)81414-3

Ethoxycarbonylnitrene (EtOCON) generated by α-elimination adds cleanly to allylic ethers giving substituted aziridines.Similar addition via nitrenium ion (EtOCONH⁺) gives derivatives of β-amino alcohols.

Full text of DOI:10.1016/S0040-4039(01)81414-3

Products guided by the article

Product name:2-Phenoxymethyl-aziridine-1-carboxylic acid ethyl ester

Cas No:93548-52-8

R&D Labs maybe for 93548-52-8

taizhou creating bio-pharm co.,ltd.

Contact:+86- 576- 88827176

Address:715 room ,unit A.junyue Building,Jiaojiang,Taizhou,Zhejiang,China
Shanghai Harvest Chemical Ind. Co., Ltd.

Contact:021-51385350

Address:ROOM 806-807, AI LI CHEN BUILDING, No.333 JINGXIANG ROAD, PUDONG DISTRICT, 201206, SHANGHAI
TIANJIN FESTO CHEMICAL CO.,LTD(expird)

Contact:86-22-25814570

Address:No.12th,5th Ave.,TEDA,Tianjin,China
Shanghai Yurui Biotechnology(Anyang) Pharmaceutical Co., Ltd

Contact:+86-0372-3662335 +86-0372-3661988

Address:hanling industrial park anyang
LIANYUNGANG YC FINE CHEMICAL CO., LTD

Contact:+86-518-858 99188

Address:Shangdong Modern Bldg, South Greenpark Road, Lianyungang, Jiangsu Pro. China

Relevant to this article

Synthesis of Orthogonally N-Protected, C-4 Functionalized Cyclic Guanidines from l -Serine

Doi:10.1055/s-0036-1589935
(2017)
[1,1′-bis(diphenylphosphino)ferrocene]dichloropalladium/1, 1′-bis(diphenylphosphino)ferrocene catalyzed synthesis of 2,3-diamino-1,4-naphthoquinones

Doi:10.1055/s-2007-965983
(2007)
Efficient synthesis of propargylic ethers under the DBU conditions and its application to natural products synthesis

Doi:10.1246/bcsj.80.578
(2007)
Investigation of the synthetic and mechanistic aspects of the highly stereoselective transformation of α-thioamides to α-thio-β- chloroacrylamides

Doi:10.1039/b618540a
(2007)
Biosynthesis of Stereoisomers of Dill Ether and Wine Lactone by Pleurotus sapidus

Doi:10.1021/acs.jafc.8b07263
(2019)
Probing the mechanism of aldehyde addition to a disuene and two silenes: Solvent effects

Doi:10.1021/om900673n
(2010)

Article Doi