ADDITION REACTIONS OF ETHOXYCARBONYLNITRENE AND ETHOXYCARBONYLNITRENIUM ION TO ALLYLIC ETHERS

DOI: 10.1016/S0040-4039(01)81414-3

Source and publish data:

Tetrahedron Letters p. 4271 - 4274 (1984)

Update date:2022-08-05

Topics:

Authors:

Loreto, M. Antonietta

Pellacani, Lucio

Tardella, Paolo A.

Toniato, Elena

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Article abstract of DOI:10.1016/S0040-4039(01)81414-3

Ethoxycarbonylnitrene (EtOCON) generated by α-elimination adds cleanly to allylic ethers giving substituted aziridines.Similar addition via nitrenium ion (EtOCONH⁺) gives derivatives of β-amino alcohols.

Full text of DOI:10.1016/S0040-4039(01)81414-3

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