Inorganica Chimica Acta p. 226 - 228 (1998)
Update date:2022-08-05
Topics:
Hill, Geoffrey S.
Holah, David G.
Hughes, Alan N.
Prokopchuk, Ernest M.
Treatment of a suspension of cis-RuCl2(Ph2PCH2PPh2)2 in ethanol or 2-propanol with a large excess of KOH leads, in a very clean reaction and in less than 2 min when ethanol is used, to the formation of cis/trans-RuH2(Ph2PCH2PPh2) 2 in yields of up to 90%. Similar treatment of the cis-dichloro complex with a small excess of KOH gives, over a longer period, trans-RuHCl(Ph2PCH2PPh2)2 in 64% yield and this complex can, in turn, be converted under similar conditions into the cis/trans-dihydride in moderate yields. trans-RuCl2(Ph2PCH2Ph2)2 is unreactive under these conditions.
Contact:+86-574-87065746
Address:10th Floor, No.787 Baizhang East Road,
Wuhan Sunrise Pharmaceutical Technology Co., Ltd
Contact:+86-27-83314682
Address:Room 340, New material Industrial base No.17, Gu Tian Five Lu , Qiaokou District, Wuhan , China
SHENYANG COMEBOARD TECHNOLOGY CO., LTD
Contact:+86-24-25724626
Address:Room2210,Tianbao International Building,No.8-1 Weigong South Street,Tiexi District,Shenyang,China
Contact:+86-15995924277
Address:WuZhongOu suzhou new south road 89
Contact:+ 86 512 52491118
Address:1 Fuyu Road, Haiyu TownChangshu, Jiangsu, China
Doi:10.1021/ol0706307
(2007)Doi:10.1039/c4ra16627b
(2015)Doi:10.1081/NCN-200061895
(2005)Doi:10.1016/j.ejmech.2008.04.017
(2009)Doi:10.1007/BF01145803
(1989)Doi:10.1016/S0040-4039(00)95755-1
(1987)
