INTRAMOLECULAR ACYLATION OF α-SULFINYL CARBANION A NEW GENERAL ROUTE TO 5-METHYLENE-2-CYCLOPENTENONES

DOI: 10.1016/S0040-4039(01)90204-7

Source and publish data:

Tetrahedron Letters p. 4141 - 4144 (1984)

Update date:2022-08-04

Topics:

Authors:

Pohmakotr, Manat

Chancharunee, Sirirat

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)90204-7

A convenient synthesis of 5-methylene-2-cyclopentenones including Methylenomycin B involving the intramolecular acylation of α-sulfinyl carbanion followed by methylation and pyrolysis is described.

Full text of DOI:10.1016/S0040-4039(01)90204-7

Products guided by the article

Product name:Hexanamide, 2-[1-hydroxy-3-(phenylsulfinyl)propyl]-N-methyl-N-phenyl-

Cas No:93766-61-1

R&D Labs maybe for 93766-61-1

Cartoon Ingredients Co., Ltd

website:http://www.cartoonchem.com/

Contact:+86-25-58074918

Address:Room 2109, RuiHua Business Center,315 South ZhongShan Road, Nanjing 210001, China
Oceachem Group Limited

website:http://www.oceanchem-group.com

Contact:86-536-8596048

Address:9th floor,Building B future Plaza, No.88.Fenghuang Street,Weifang,Shandong,China
Chengdu Gelipu Biotechnology Co., Ltd.

website:http://www.glp-china.com

Contact:86-28-82610909

Address:chegndu
Jintan Jinnuo Chemical Co., Ltd.

Contact:+86-519-80199901

Address:Room 1804, Building 1, Huacheng Business Plaza, Jintan, Jiangsu, China
Lishui Nanming Chemical Co., Ltd(expird)

Contact:+86-0578-2134101，2697830

Address:No.19 Tongji Road Shuige Industrial zone

Relevant to this article

Further studies with the 2-amino-1,3-thiazol-4(5H)-one class of 11β-hydroxysteroid dehydrogenase type 1 inhibitors: Reducing pregnane X receptor activity and exploring activity in a monkey pharmacodynamic model

Doi:10.1021/jm801073z
(2008)
First total synthesis of N-oxido-3-aza-1,3,5(10)-trieno Steroids

Doi:10.1055/s-2005-869879
(2005)
Disilyl complexes of zirconium, hafnium, and tantalum. Their synthesis, characterization, and exchanges with silyl anions

Doi:10.1021/om050302f
(2005)
Crystal structures of rat vitamin D receptor bound to adamantyl vitamin D analogs: Structural basis for vitamin D receptor antagonism and partial agonism

Doi:10.1021/jm8004477
(2008)
Amidoalkylation reactions of anilines. A direct synthesis of benzodiazepines

Doi:10.1021/jo00165a034
(1983)
Pyrazolo[4,3-b]pyrimido[4,5-e][1,4]diazepine derivatives as new multi-targeted inhibitors of Aurora A/B and KDR

Doi:10.1016/j.ejmech.2018.09.032
(2018)

Article Doi