INTRAMOLECULAR ACYLATION OF α-SULFINYL CARBANION A NEW GENERAL ROUTE TO 5-METHYLENE-2-CYCLOPENTENONES

DOI: 10.1016/S0040-4039(01)90204-7

Source and publish data:

Tetrahedron Letters p. 4141 - 4144 (1984)

Update date:2022-08-04

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Authors:

Pohmakotr, Manat

Chancharunee, Sirirat

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Article abstract of DOI:10.1016/S0040-4039(01)90204-7

A convenient synthesis of 5-methylene-2-cyclopentenones including Methylenomycin B involving the intramolecular acylation of α-sulfinyl carbanion followed by methylation and pyrolysis is described.

Full text of DOI:10.1016/S0040-4039(01)90204-7

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