A Simple Synthesis of the Tropone Nucleus

DOI: 10.1039/c39840000743

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 743 - 744 (1984)

Update date:2022-09-26

Topics: Synthesis Catalyst Isolation Solvent Reactants Purification

Authors:

Barbier, Michel

Barton, Derek H. R.

Devys, Michel

Topgi, Ravindra Satish

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39840000743

Reduction of suitably substituted dichloro- or dibromo-methylcyclohexadienones with tributyltin hydride affords tropones (or tropolones) in medium to excellent yield; ortho- and para-substituted cyclohexadienones afford the same tropone.

Full text of DOI:10.1039/c39840000743

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:2,4-Cyclohexadien-1-one, 6-(dichloromethyl)-2,4-bis(1,1-dimethylethyl)-6-(1-methylethoxy)-

Cas No:93847-44-0

R&D Labs maybe for 93847-44-0

CHANGZHOU HANGYU PHARMACEUTICAL TECHNOLOGY CO., LTD

website:http://www.czyys.com

Contact:0086-519-88802789

Address:No.300,Yanling Middle Road, Changzhou, Jiangsu, China
zhejiang huangyan wanfeng pharm chem co.ltd

Contact:+86-576- 84160728

Address:No. 5 Dazha Road, Economic,Development Zone(JiangKou), Zhejiang, China
shijiazhuang baisheng chem co.; ltd

Contact:86-0311-80790826

Address:shijiazhuang hebei
Changzhou Ansciep Chemical Co.,Ltd.

Contact:+86 519 8630 5871

Address:A-710 Boan International, 8 East Guangdian Road,Wujin,Changzhou
zhuzhou zhongle chemical co. ltd.

Contact:+86-0731 28228409

Address:Zhuzhou, Hunan, China

Relevant to this article

Iron(III)-catalyzed C-H functionalization: Ortho-benzoyloxylation of N,N-dialkylanilines and its application to 1,4-benzoxazepines

Doi:10.1002/ejoc.201402751
(2014)
Design and synthesis of novel quinolinone-3-aminoamides and their α-lipoic acid adducts as antioxidant and anti-inflammatory agents

Doi:10.1021/jm061173n
(2007)
Human platelets and polymorphonuclear leukocytes synthesize oxygenated derivatives of arachidonylethanolamide (anandamide): Their affinities for cannabinoid receptors and pathways of inactivation

Doi:10.1124/mol.54.1.180
(1998)
Relationship between hydrophobicity and antioxidant ability of "phenolipids" in emulsion: A parabolic effect of the chain length of rosmarinate esters

Doi:10.1021/jf904119v
(2010)
Synthesis, nanostructures, and functionality of amphiphilic liquid crystalline block copolymers with azobenzene moieties

Doi:10.1021/ma011859j
(2002)
Enantioselective Formation of CF₃-Bearing All-Carbon Quaternary Stereocenters via C-H Functionalization of Methanol: Iridium Catalyzed Allene Hydrohydroxymethylation

Doi:10.1021/jacs.7b04374
(2017)

Article Doi