Arylation of Olefins by N-Nitroso-N-arylacetamides under Palladium(0) Catalysis: A New Precursor of Arylpalladium Species

DOI: 10.1021/jo00203a003

Source and publish data:

Journal of Organic Chemistry p. 299 - 301 (1985)

Update date:2022-08-05

Topics:

Authors:

Kikukawa, Kiyoshi

Naritomi, Masaki

He, Gong-Xin

Wada, Fumio

Matsuda, Tsutomu

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Article abstract of DOI:10.1021/jo00203a003

Olefins (styrene, octene-1, cycloheptene, ethyl acrylate, and vinyl acetate) were easily arylated in good yields with N-nitroso-N-arylacetamides (ArN(NO)COCH3: Ar= Ph, 4-MeC6H4, 4-MeOC6H4, 4-ClC6H4, 4-BrC6H4, and 4-IC6H4) under palladium(0) catalysis at 40 deg C within 40 min.

Full text of DOI:10.1021/jo00203a003

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