Base-induced Rearrangement of the O-Methanesulphonyl Derivatives of N-(Alkylphenylphosphinoyl)hydroxylamines. Highly Selective Migration of the Phenyl Group

DOI: 10.1039/c39840001140

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Journal of the Chemical Society. Chemical communications p. 1140 - 1141 (1984)

Update date:2022-08-05

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Authors:

Harger, Martin J. P.

Smith, Adrian

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Article abstract of DOI:10.1039/c39840001140

The N-(alkylphenylphosphinoyl)-O-methanesulphonylhydroxylamines RPhP(O)NHOSO2Me (R = Me, Et, or Prⁱ) react readily with MeNH2 or NaOMe-MeOH to give products resulting from phenyl, but not alkyl, migration.

Full text of DOI:10.1039/c39840001140

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