Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy p. 995 - 998 (1984)
Update date:2022-07-29
Topics:
Alvarez-Valdes, A.
Masaguer, J. R.
Garcia-Vazquez, J. A.
Complexes of antimony pentachloride were prepared with benzonitrile, 2,3- and 4-methyl-benzonitriles, and 2,3-; 2,4-; 2,5- and 3,4-dimethylbenzonitriles of type SbCl5.L.All the isolated solids were non-electrolytes in nitromethane.The i.r. and Raman spectral data of the complexes are in good agreement with local C4v symmetry for the SbCl5N moiety.A classification of the donor strength of benzonitriles is proposed.
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