A Nitrile Oxide Based Entry to 2,3-Dihydropyran-4-ones. Synthesis of a Protected Version of "Compactin Lactone" in Racemic and Optically Active Forms

DOI: 10.1021/jo00206a010

Source and publish data:

Journal of Organic Chemistry p. 778 - 785 (1985)

Update date:2022-08-04

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Authors:

Kozikowski, Alan P.

Li, Chun-Sing

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Article abstract of DOI:10.1021/jo00206a010

The use of nitrile oxides bearing a masked β-oxo group as β-hydroxy-3-oxopropionylating agents for the vicinal functionalization of olefins is described.The β-hydroxy ketones revealed on hydrogenation of the initially formed 1,3-dipolar cycloaddition prod

Full text of DOI:10.1021/jo00206a010

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