Palladium-imidazolinium carbene-catalyzed arylation of aldehydes with arylboronic acids in water

DOI: 10.1016/j.tet.2010.06.049

Source and publish data:

Tetrahedron p. 6814 - 6819 (2010)

Update date:2022-07-29

Topics:

Authors:

Kuriyama, Masami

Ishiyama, Natsuki

Shimazawa, Rumiko

Onomura, Osamu

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Article abstract of DOI:10.1016/j.tet.2010.06.049

The catalytic arylation of aldehydes with arylboronic acids in only water was found to be achieved using the palladium/thioether-imidazolinium chloride system in good to excellent yields. This catalytic process showed high tolerance for a broad range of substrates, giving a variety of carbinol derivatives with 2.0-3.0 mol % of the catalyst.

Full text of DOI:10.1016/j.tet.2010.06.049

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