Enantioselective total synthesis of cyathin A3

DOI: 10.1021/ol070994z

Source and publish data:

Organic Letters p. 2843 - 2846 (2007)

Update date:2022-08-03

Topics:

Authors:

Ward, Dale E.

Shen, Jianheng

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Article abstract of DOI:10.1021/ol070994z

The total synthesis of (-)-cyathin A₃ is described. The key step involves an unusual enantioselective Diels Alder reaction of 2,5-dimethyl1,4-benzoquinone with 2,4-bis(trimethylsilyloxy)-1,3-pentadiene, using Mikami's catalyst [(R)-BINOL + Cl View More

Full text of DOI:10.1021/ol070994z

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