Bis(dialkylphosphino)methane Complexes of Palladium(II) and the Molecular Structure of iPCH2PPri2)(μ-Pri2PCH2PHPri)>.2CHCl3 containing an Unusual Phosphidophosphine Bridging Ligand

DOI: 10.1039/DT9870000201

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 201 - 206 (1987)

Update date:2022-08-04

Topics:

Authors:

Manojlovic-Muir, Ljubica

Lloyd, Brian R.

Puddephatt, Richard J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9870000201

The mononuclear chelate complexes (X = CF3CO2 or Cl; R = Me, Et, or Prⁱ) have been prepared and characterized spectroscopically.Reaction of with Prⁱ2PCH2PHPrⁱ gave a novel binuclear complex, iPCH2PPrⁱ2)(μ-Prⁱ2PCH2PHPrⁱ)>, with the phosphidophosphine ligand in an unusual bridging mode.This complex was characterized by 1H and 31P n.m.r. spectroscopy and by X-ray crystal-structure analysis of its trichloromethane solvate , a = 8.744(2), b = 11.483(1), c = 20.108(4) Angstroem, α = 103.49(1), β = 97.15(2), γ = 91.11(2) deg, Z = 2, R = 0.035 for 5 918 symmetry-independent reflections with I >/= 3?(I)>.

Full text of DOI:10.1039/DT9870000201

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:{bis(diphenylphosphino)methane}bis(trifluoroacetato)palladium(II)

Cas No:94791-45-4

R&D Labs maybe for 94791-45-4

Suzhou Sibian Chemical Technology Co., Ltd

website:http://www.sibianpharm.com

Contact:+8618169181984,+8618013186906

Address:Room1404,BuildingA,Jiabao Square No.323 Baodai East Road,Wuzhong District,Suzhou Jiangsu China (215128)
Changsha Yonta Industry Co., Ltd.

Contact:+ 86-731-8535 2228

Address:Rm.1717, North Bldg., No.368, East 2nd Ring Road(2nd Section)
Baoding City Light Industry And Textiles Imp.& Exp. Corp. Chemical Department.

Contact:86-312-3262436

Address:NO.658 CHAOYANG SOUTH STREET,BAODING CITY HEBEI CHINA
Chengdu Gelipu Biotechnology Co., Ltd.

website:http://www.glp-china.com

Contact:86-28-82610909

Address:chegndu
Sinoway Industrial Co., Ltd.

website:http://www.china-sinoway.com

Contact:+86-592-5853819

Address:16/F,Huicheng Comm,Complex,No839 XiaHe Rd, Xiamen,China

Relevant to this article

CONFORMATIONS OF SATURATED SIX-MEMBERED-RING PHOSPHOROUS HETEROCYCLES. CHAIR-CHAIR EQUILIBRIA FOR CYCLOPHOSPHAMIDE, THE 5,5-DIMETHYL DERIVATIVE, AND RELATED 1,3,2-OXAZAPHOSPHORINANES. RELATIVE CONFORMATIONAL ENERGIES OF NITROGEN MUSTARD AND OTHER R_2<

Doi:10.1021/ja00293a044
(1985)
Polymer-supported thiobenzophenone: a self-indicating traceless 'catch and release' linker for the synthesis of isothiocyanates

Doi:10.1016/j.tetlet.2007.06.025
(2007)
Synthesis, characterization, and antioxidant activity of heterocyclic Schiff bases

Doi:10.1002/jccs.202000161
(2020)
Doi:10.1002/hlca.193802101182
(1938)
Light-fluorous safety-catch arylgermanes - Exceptionally robust, photochemically activated precursors for biaryl synthesis by Pd(0) catalysed cross-coupling

Doi:10.1039/b707517k
(2007)
Chemoenzymatic synthesis of a MUC1 glycopeptide carrying non-natural sialyl TF-β O-glycan

Doi:10.1271/bbb.60244
(2006)

Article Doi