The Intramolecular Diene-Carbene Cycloaddition Equivalence and an Enantioselective Birch Reduction-Alkylation by the Chiral Auxiliary Approach. Total Synthesis of (+/-)- and (-)-Longifolene

DOI: 10.1021/jo00206a049

Source and publish data:

Journal of Organic Chemistry p. 915 - 916 (1985)

Update date:2022-08-03

Topics:

Authors:

Schultz, Arthur G.

Puig, Salvador

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00206a049

Total syntheses of racemic and optically pure (-)-longifolene (1) illustrate (1) a preparation of 6-alkyl-6-(methoxycarbonyl)-2,4-cyclohexadien-1-ones (e.g., 5a) by Birch reduction-alkylation of methyl o-methoxybenzoate and the chiral benzoic acid derivat

Full text of DOI:10.1021/jo00206a049

Products guided by the article

Product name:(S)-1-(4,4-Dimethyl-5-oxo-pentyl)-6-oxo-cyclohex-2-enecarboxylic acid (S)-1-pyrrolidin-2-ylmethyl ester

Cas No:94978-40-2

R&D Labs maybe for 94978-40-2

Weifang Dongxing Chitosan Factory

website:http://dxchitosan.lookchem.com/

Contact:13475651157

Address:Weifang city ,shandong province
Wuhan Hanye Chemical New Material Co.,Ltd

Contact:+86-27-85308141

Address:LiuDian, Panlongcheng Economic Development Zone, HuangPi district, Wuhan, Hubei 430311 P.R.China
Shanghai SMEC Trading Co., Ltd.

website:http://www.shanghaismec.com

Contact:+86-21-68811293

Address:ROOM 1101,NO.800 SHANGCHENG RD,SHANGHAI,CHINA
Xi'an yuanfar international trade company

website:https://www.yuanfarchemical.com

Contact:86-029-88745613 ext 828

Address:Floor19th ,B Building, Oak Block,No.36 South Fenghui Road, Dev. Zone of High-Tech Ind.,Xi’an, China
Laizhou City Laiyu Chemical CO.,Ltd

Contact:+86-535-2719337/2719339

Address:Chenggang road zhuyou laizhou City Shangdong China

Relevant to this article

Asymmetric Synthesis of (R)-1-Alkyl-Substituted Tetrahydro-?-carbolines Catalyzed by Strictosidine Synthases

Doi:10.1002/anie.201803372
(2018)
(tmp)₂Zn·2 MgCl₂·2 LiCl: A chemoselective base for the directed zincation of sensitive arenes and heteroarenes

Doi:10.1002/anie.200701984
(2007)
Regio- and stereospecific formation of protected allylic alcohols via zirconium-mediated S_N2′ substitution of allylic chlorides

Doi:10.1021/ja075967i
(2007)
Alkyl and aryl compounds of rhodium(III) and iridium(III) supported by 4,4′-Di-tert-butyl-2,2′-bipyridyl

Doi:10.1021/om7006216
(2007)
Discovery of pyrazolyl propionyl cyclohexenamide derivatives as full agonists for the high affinity niacin receptor GPR109A

Doi:10.1016/j.bmcl.2010.04.013
(2010)
INTRAMOLECULAR ALKYLATION OF VINYLGERMANES AND IODODEGERMYLATION OF 1-CYCLOALKENYLGERMANES

Doi:10.1246/cl.1985.53
(1985)

Article Doi