NEW FORMATION OF A 1,3-DIPOLE IN THE REACTION OF ADAMANTANONE AZINE WITH TRIAZOLINEDIONES: IN CONNECTION WITH REACTIVITY TOWARD SINGLET OXIGEN

DOI: 10.1016/S0040-4039(01)81511-2

Source and publish data:

Tetrahedron Letters p. 4757 - 4760 (1984)

Update date:2022-07-31

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Authors:

Akasaka, Takeshi

Sonobe, Hideki

Sato, Rikiya

Ando, Wataru

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Article abstract of DOI:10.1016/S0040-4039(01)81511-2

Tricyclo(3.3.1.1)decanone azine(adamantanone azine)reacts with 4-substituted 1,2,4-triazoline-3,5-diones under elimination of diazo adamantane to give a 1,3 dipole("azomethinimine"), which on treatment with dipolarophiles affords the (2+3)-cycloadducts.The reaction is compared with singlet oxygen oxidation.

Full text of DOI:10.1016/S0040-4039(01)81511-2

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