Tetrahedron Letters p. 4757 - 4760 (1984)
Update date:2022-07-31
Topics:
Akasaka, Takeshi
Sonobe, Hideki
Sato, Rikiya
Ando, Wataru
Tricyclo(3.3.1.1)decanone azine(adamantanone azine)reacts with 4-substituted 1,2,4-triazoline-3,5-diones under elimination of diazo adamantane to give a 1,3 dipole("azomethinimine"), which on treatment with dipolarophiles affords the (2+3)-cycloadducts.The reaction is compared with singlet oxygen oxidation.
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(1986)
