Tetrahedron Letters p. 5251 - 5254 (1984)
Update date:2022-08-02
Topics:
Seyferth, Dietmar
Hui, Richard C.
The reactions of t-BuLi, sec-BuLi and n-BuLi with CO in the presence of isothiocyanates and isocyanates gives, after hydrolytic work-up, α-oxothioamides, RC(O)C(S)NHR', and α-oxoamides, RC(O)C(O)NHR', respectively, in good yield.Competition from the direct reaction of RLi with the substrate is encountered only in the case of reactions of the n-BuLi/CO system with isocyanates.
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(1984)
