Journal of the Chemical Society, Dalton Transactions p. 1373 - 1377 (1996)
Update date:2022-08-04
Topics:
Jackson, Graham E.
Nakani, Bandile S.
Copper(II) and H+ complexes of 3,3,8,8-tetramethyl-4,7-diazadecane-2,9-dione dioxime, 3,3,9,9-tetramethyl-4,8-diazaundecane-2,10-dione dioxime and 3,3,10,10-tetramethyl-4,9-diazadodecane-2,11-dione dioxime have been studied at 25°C and ionic strength 0.15 mol dm-3 NaCl, using glass-electrode potentiometry. Electronic spectra have been used to postulate structures for the different species in solution. In each case the metal binds to the four nitrogen atoms of the oxime. In the MLH-1 species hydrogen bonding between the terminal oxime groups produces a pseudo-macrocycle. Computer simulation has been used to predict the effect of the ligands on the blood-plasma metal-ion distribution in vivo.
View MoreCerametek Materials（ShenZhen）Co., Ltd.
Contact:+86-755-2324.2554
Address:A3-#9, YongChuan Street, Suite 501
Nanjing Qirui Material Co., Ltd.
Contact:+86-25-52320053
Address:F4-5, #17 Building, Chuang Yi Yuan, No.6 Guanghua East Street, Nanjing, 210007 P.R.China
Synchem Pharma Co.,Ltd(expird)
Contact:+0086-21-61984905-1
Address:Building 60,Zimian Park, LongYang industrial Area, 1515Nong，Yuandong Road Fengxian District, Shanghai ,China
Contact:+86-535-8888888
Address:No.161 Haishi Rd.
SHANGHAI T&W PHARMACEUTICAL CO., LTD.
website:http://www.trustwe.com
Contact:+86-21-61551413
Address:601, No. 1, 2277 Nong, Zu Chongzhi Road, Zhangjiang Hightech. Park, Pudong
Doi:10.1063/1.870409
(1936)Doi:10.1021/ja00891a012
(1963)Doi:10.1021/ja00294a027
(1985)Doi:10.1039/jr9490002342
(1949)Doi:10.1016/j.poly.2007.06.012
(2007)Doi:10.1007/s00706-008-0886-4
(2008)
