Journal of the Chemical Society, Dalton Transactions p. 1373 - 1377 (1996)
Update date:2022-08-04
Topics:
Jackson, Graham E.
Nakani, Bandile S.
Copper(II) and H+ complexes of 3,3,8,8-tetramethyl-4,7-diazadecane-2,9-dione dioxime, 3,3,9,9-tetramethyl-4,8-diazaundecane-2,10-dione dioxime and 3,3,10,10-tetramethyl-4,9-diazadodecane-2,11-dione dioxime have been studied at 25°C and ionic strength 0.15 mol dm-3 NaCl, using glass-electrode potentiometry. Electronic spectra have been used to postulate structures for the different species in solution. In each case the metal binds to the four nitrogen atoms of the oxime. In the MLH-1 species hydrogen bonding between the terminal oxime groups produces a pseudo-macrocycle. Computer simulation has been used to predict the effect of the ligands on the blood-plasma metal-ion distribution in vivo.
View MoreEvergreen Chemical Industry Ltd.
Contact:86-553-4918210
Address:6#2-602 Wanhaobailing
Winchem Industrial Co. Ltd.(expird)
Contact:86-574-83851061 86-574-87083208
Address:Room 905, No.3 Building,East Business Center, 456 Xingning Road, Ningbo City,China
Hangzhou Pharma & Chem Co.,Ltd.
Contact:+86-571-87040515
Address:No,139Qingchun Rd
Contact:+86-10-62651721
Address:29 Yongxing Road, Daxing District,Beijing China
Chengdu Pukang Biotechnology Co., Ltd
Contact:+86-28-82550498
Address:No. 558 Rulin Road,Xinjin county,Chengdu city, China
Doi:10.1063/1.870409
(1936)Doi:10.1021/ja00891a012
(1963)Doi:10.1021/ja00294a027
(1985)Doi:10.1039/jr9490002342
(1949)Doi:10.1016/j.poly.2007.06.012
(2007)Doi:10.1007/s00706-008-0886-4
(2008)
