Journal of Organic Chemistry p. 1143 - 1144 (1985)
Update date:2022-09-26
Topics:
Midland, M. Mark
Gabriel, Josef
The spiroketal talaromycin A has been prepared in high optical and diastereomeric purity by using a <2,3>-sigmatropic (Wittig) rearrangement and a <3,3>-Claisen rearrangement as key steps in controlling absolute configuration.
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