Synthesis of (-)-Talaromycin A

DOI: 10.1021/jo00207a053

Source and publish data:

Journal of Organic Chemistry p. 1143 - 1144 (1985)

Update date:2022-09-26

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Authors:

Midland, M. Mark

Gabriel, Josef

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Article abstract of DOI:10.1021/jo00207a053

The spiroketal talaromycin A has been prepared in high optical and diastereomeric purity by using a <2,3>-sigmatropic (Wittig) rearrangement and a <3,3>-Claisen rearrangement as key steps in controlling absolute configuration.

Full text of DOI:10.1021/jo00207a053

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