Threophos: A New Chiral Aminophosphine Phosphinite (AMPP) Ligand Highly Efficient in Asymmetric Hydrovinylation of Cyclohexa-1,3-diene Catalyzed by Nickel Complexes

DOI: 10.1021/jo00210a051

Source and publish data:

Journal of Organic Chemistry p. 1781 - 1782 (1985)

Update date:2022-07-29

Topics:

Authors:

Buono, Gerard

Siv, Chhan

Peiffer, Gilbert

Triantaphylides, Christian

Denis, Philippe

et al. et al.

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Article abstract of DOI:10.1021/jo00210a051

Threophos is a potential tridentate ligand obtained from threonine. (S)-(+)-3-Vinylcyclohex-1-ene is produced quantitatively in 93percent ee from asymmetric hydrovinylation of cyclohexa-1,3-diene catalyzed by the Ni(COD)2-AlEt2Cl-<(2R,3R)-threophos> syste

Full text of DOI:10.1021/jo00210a051

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