APPLICATIONS OF INTRAMOLECULAR DIELS-ALDER REACTIONS OF HETERODIENES. FACILE SYNTHESES OF HETEROYOHIMBINE ALKALOIDS TETRAHYDROALSTONINE AND AKUAMMIGINE

DOI: 10.1016/S0040-4039(01)91244-4

Source and publish data:

Tetrahedron Letters p. 4863 - 4866 (1984)

Update date:2022-08-03

Topics: Regioselectivity NMR spectroscopy Mass spectrometry Chromatography Total synthesis Retrosynthetic analysis Heterodiene Stereoselectivity Cycloaddition Catalysis Conformational Analysis Intramolecular Diels-Alder Reaction Dienophile Ring Strain Diene Reaction yield synthetic intermediate

Authors:

Martin, Stephen F.

Benage, Brigitte

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Article abstract of DOI:10.1016/S0040-4039(01)91244-4

A facile, formal synthesis of the heteroyohimbine alkaloids tetrahydroalstonine (1) and akuammigine (2) has been completed in which the D/E ring system is constructed by the novel cyclization of the triene 10, a process which involves the intramolecular <

Full text of DOI:10.1016/S0040-4039(01)91244-4

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