Synthesis and Crystal Structure of the η2-Bonded CSe2 Complex 2-CSe2)>.C6H6 2PCH2)3CMe>. Metal-promoted Head-to-head Dimerizatio

DOI: 10.1039/c39840001647

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1647 - 1649 (1984)

Update date:2022-07-30

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Authors:

Bianchini, Claudio

Mealli, Carlo

Meli, Andrea

Sabat, Michal

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Article abstract of DOI:10.1039/c39840001647

The reaction of CSe2 with 2 and triphos gives <(triphos)RhCl(η²-CSe2)>.C6H6, X-ray analysis of which shows that CSe2 is η²-bonded via C and Se; the action of Lewis acids on this η²-CSe2

Full text of DOI:10.1039/c39840001647

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